Fragmentation shield for impact resisting optical medium

ABSTRACT

A fragmentation shield having capability of preventing fragmented particles of the shield material from becoming airborne due to high velocity impact is disclosed. The shield is in the form of a laminate including a plurality of layers of optical material and interposed bonding material layers or monolithic plastic. The bonding material or plastic displays an index of refraction closely matching that of the optical material. The shield is supported by a frame. A fragment shield likewise is supported by the frame. The fragment shield is disposed in parallel spaced relation to the laminate or plastic thereby to provide a closed air space therebetween.

United States Patent 1 1 1 1 3,917,891

Cooke et al. 11 Nov. 4, 1975 [54] FRAGNIENTATION SHIELD FOR IMPACT 3,657,057 4/1972 Schorr et al. 156/99 X RES OPTICAL MEDIUM 3,671,370 6/1972 Littell, J r. 156/99 X 3,762,981 lO/1973 Blank 156/99 X Inventorsi William Cooke; Albert g 3,864,204 2/1975 Shorr et al. l6l/l99 x both of Kingsport, Tenn.

[73] Assignee: ASG Industries Inc., Kingsport, Primary Examiner-Philip et T Attorney, Agent, or Firm-Pennie & Edmonds [22] Filed: Apr. 11, 1974 [57] ABSTRACT [21] Appl. No.: 460,013

A fragmentation shield having capability of preventing fragmented particles of the :shield material from becoming airborne due to high velocity impact is disclosed. The shield is in the form of a laminate including a plurality of layers of optical material and inter- [52] US. Cl. 428/337; 89/36; 156/107; 156/109; 428/339; 428/438; 428/441; 428/911 [51] Int. posed bonding material layers or monolithic plastic. Field of Search CO3C 27/10 5 2 34 The bonding material or plastic displays an index of refraction closely matching that of the optical material. The shield is supported by a frame. A fragment shield likewise is supported by the frame. The fragment shield is disposed in parallel spaced relation to [5 6] References Cited the laminate or plastic thereby to provide a closed air UNITED STATES PATENTS space therebetween.

2,145,930 2/1939 Herron 156/107 2,991,209 7/1961 Worrall... 156/99 x 17 3 D'awmg F'gures 3,630,814 12/1971 Arnold 89/36 A X FRAGMENTATION SHIELD FOR IMPACT RESISTING OPTICAL MEDIUM The present invention relates to an optical product having capability of preventing possible fragmentations from the optical medium from becoming airborne away from the product. More particularly, the invention relates to a bullet resisting product including a laminate of a plurality of bullet resisting glass panels bonded together by a bonding agent with an index of refraction closely matching that of the glass, a fragment shield and a frame for supporting both the laminate and the shield in parallel, spaced disposition.

BACKGROUND OF THE INVENTION The manufacture of laminated bullet resisting glass is well known and widely practiced. Such bullet resisting glass is conventionally fabricated from a number of layers of plate or float glass (i.e., a term applied to the product of a manufacturing process during which the glass product is formed upon a molten bath of tin) and interposed layers of bonding material having an index of refraction closely matching that of the glass being used. A commonly used bonding agent is polyvinyl butyral plastic film. The several layers are bonded together under conditions of heat and pressure to form the laminate.

Bullet resisting glass generally is fabricated in thicknesses which may vary from about 1 3/16 inches to about 2 inches. Thicker composites are common for military applications.

Both plate and float glass are brittle and by themselves have poor impact resistance. When layers of glass are laminated with polyvinyl butyral plastic, it has been found that the elastic strength of the plastic is incorporated into the composite mass. This greatly increases the impact resistance of each layer of glass by spreading the shock waves and by holding together the broken glass fragments in the immediate vicinity of the point of impact. The elastic strength, rigidity, and adhesion of the plastic to the glass play important roles in the overall bullet resistance of the composite make up. Normally the plastic bonding layer will be in the range of approximately 15 mils in thickness and the plasticizer content of the plastic may vary from 46 parts down to about 21 parts depending on the application and end use of the product. It is common practice to bond the glass layers with polyvinyl butyral of a thickness of 15 mils. In commercial applications the polyvinyl butyral normally contains 46 parts plasticizer whereas military specifications usually call for polyvinyl butyral containing 21 parts plasticizer for all applications.

Presently available products utilizing alternately a 15 mil thickness bonding layer between, for example, four 1 inch glass plates and a single 1% inch glass combining in an overall 1 3/16 inch thick medium power bullet resisting glass have been found to use a low content (in parts) of plasticizer in the bonding material. To this end polyvinyl butyral containing 21 parts plasticizer may be used so that the product passes an impact and spall penetration test. However, polyvinyl butyral containing 21 parts plasticizer is very stiff and difficult to sandwich between the glass layers. Further, this bonding material has a powdered interleaving which requires removal by washing before use. The resultant laminated product contains excessive defects which detract from its overall appearance and render it economically impracticable.

BRIEF DESCRIPTION OF THE INVENTION The present invention seeks to provide in a similar product of 1 3/16 inch thickness utilizing a polyvinyl butyral plastic bonding agent including a plasticizer content (in parts) on the high side to pass an impact and spall penetration test.

In an important aspect, the present invention is directed to a bullet resisting glass product including a plurality of layers of optical material bonded together into a laminate which is supported by a frame member. The frame member also supports a fragment shield in spaced, parallel relationship relative to the laminate.

The laminate may include layers of either optical plastic, such as polycarbonate or acetate butyrate, or glass, either plate, float or sheet (hereinafter collectively referred to as glass") and a binder. It is pre ferred to use glass panels and a binder of polyvinyl butyral having a thickness of about 15 mils and including about 40 parts plasticizer or more. The fragment shield may be either laminated glass or plastic.

In a second aspect, the present invention proposes a frame member including an internal spacing element supporting the peripheral region of both the laminate and the shield.

There has thus been outlined rather broadly the more important features of the invention in order that the detailed description thereof that follows may be better .understood and in order that the present contribution to the art may be better appreciated. There are, of course, additional features of the invention that will be described hereinafter and which will form the subject of the claims appended hereto. Those skilled in the art will appreciate that the conception upon which this disclosure is based may readily be utilized as a basis for the designing of other structures for carrying out the several purposes of the invention. It is important, the refore, that the claims be regarded as including such equivalent construction as do not depart from the spirit and scope of the invention.

DESCRIPTION OF THE DRAWING The accompanying drawing forms a part of the present application. By this drawing:

FIG. 1 is a perspective view of the bullet resisting glass product having a portion of the fragment shield broken away to illustrate the air space;

FIG. 2 is a vertical section as seen along the lines 2-2 in FIG. 1; and,

FIG. 3 is an enlargement of the upper portion of FIG. 2.

DESCRIPTION OF THE PREFERRED EMBODIMENT The drawing figures illustrate a bullet resisting barrier 10 including a plurality of layers of optically transparent material 14, 18, 20, 22, 24, interposed plastic bonding layers 19, 21, 23, 25 to permit bonding of the transparent material, a fragment shield 12, a further layer 14 of optically transparent material, and a frame construction 16 for supporting the fragment shield in spaced parallel relation to the layer 14.

Any number of layers of optically transparent material may be utilized according to the bullet resisting capability desired. For example, in addition to the layer 14, a plurality of four layers 18, 20, 22 and 24 has been 3 used successfully under test conditions and is preferred.

The optical sheets preferably are formed of glass. The sheets may be approximately 0.25 inches in thickness.

The alternate plastic bonding layers 19, 21, 23, 25 may be on the order of about mils to about 30 mils in thickness and formed from a material having an index of refraction closely; matching the index of refraction of glass. Polyvinyl butyral plastic is preferred. For ease of drafting and for clarity the interposed plastic bonding layers, being exceedingly'thin, are not shown in FIG. 2 but onl in FIG. 3.

The layer 14 may be formed'of glass and similarly bonded to layer 24 by an interposed layer of plastic 25.

The layer'14 is of a'thicknes s less than the thickness of any one of the layers'18, 20, 22 and 24. The layer 14 may be approximately 0.125 inches in thickness. The layer 14 serves the purpose of reducing the thickness and size of those fragments which may spall from the inner surface of the glass after impact of a bullet.

The layers may be laminated under heat and pressure in accordance with conventional practice in the manufacture of safety glass. The laminate which is formed will be approximately 1 3/16 inches in thickness which is withinthe limits of presently commercially recognized bullet resisting glass. By increasing the number of glass lamina sheets athicker barrier of 2 inches or more may be fabricated. As suggested, the latter construction is common in military application.

. Theimprovement of the present glass product resides 4 window glass is preferred where economy is an important consideration.

The frame 16 serves to mount the laminate formed by the layers 14, 18, 20, 22 and 24 and the fragment shield 12. As illustrated in the figures, the frame includes a top 26, bottom 28, and side members 30 (32) which may be connected in any suitable manner. A front 34 and back border member 36 provide lateral secureme'nt of the components.

A spacer 38 is disposed within the confines of the frame definedby the back member and juxtaposed to the members 26, 28, 30, 32. The spacer may be formed by a tape, such as a foam tape manufactured by the Minnesota Mining and Manufacturing Company under the trademark Scotch-Mount," a double coated tape No. 4004, which has'adhesiv'e on both surfaces, or by an extruded or otherwise formed metal member whose edges are sealed to the frame by a butyl rubber as in the case of insulated glass units, or by a wooden framing member. The wooden framing member is sealed'in like fashion whereas the foam tape may provide opposed adhesive surfaces for adherence to the layers 12 and 14.

The spacer member may be of such dimensions to provide an air gap 40 of from approximately 0.25 to about 0.875 inches in width. By means of the air gap and fragment shield fragments which spall from the glass laminate upon impact of a bullet travelling in the direction of the arrow in FIG. 2 will be trapped.

Commercial grades of bullet resisting glass are listed below:

in the use of a fragment shield 12 which is spaced from the above bullet resisting glass laminate by means of the, frame 16. As will be seen below, the fragment shield togetherwith the means to space the same from the bullet-resisting glass laminate increases the effectiveness of theassemblage without the heretofore required increase in the thickness of the glass laminate or in the reduction in plasticizer content.

The fragment shield 12 itself may be formed of various optically transparent materials. Laminated glass may be utilized. Laminated lami-lami, i.e., a lamination including two sheets (window glass) of 0.108 inch thickness and an interlayer of 0.015 inch thick polyvinyl butyral film, is the most economical thickness. For larger windows a A: inch glass plate laminated to a second A inch glass sheet may be required. The shield may also be formed from Uvex, plexiglass or sheets of acrylic plastic, or Lexan." Uvex" is a tradename of Eastman Kodak for their optically clear cellulose acetate butyrate sheet. Lexan is a tradename of General Electric for their optically clear polycarbonate. Additionally, the shield may be formed of either polished wired glass or float glass having a thickness of about one-fourth inch. While all of the above may be used as shown in FIG. 2, shield 12'comprises two laminae cross-hatched to indicate one of the plastic materials mentioned above although, as previously mentioned, the laminated lami-lami of the previously mentioned The greater the thickness the greater the resistance characteristic of the bullet resistance glass, laminated in a fashion as described.

The object of a window of bullet resisting glass is to protect personnel standing directly behind or in the immediate vicinity of the window from both bullets and fragments of glass which break loose from the inner surface of the glass. Those fragments include glass particles ranging in size from powder to pieces measuring k X 1 inches in size. The bulk of the fragments are X 54; X l/16 inches. It is common for discs of plastic ranging in size from 1% up to 3 inches in diameter to tear loose from bulges which form on the inner surface of the glass. These discs of plastic are coated on both surfaces with glass fragments. And as indicated, if the inner surface of the bullet resisting glass or layer 14 should be one-eighth inches thick the size of the glass fragments will be minimized slightly.

It is assumed that a window of bullet resisting glass will effectively stop or contain the bullets fired at it from a weapon equal to the rating of the window. From the point of impact a shock wave precedes the bullet into the glass. The bullet is contained by the glass, yet the shock wave travels through the thickness of the glass while spreading over a circular area having a diameter of 6 inches or more. This area contains broken pieces of glass which radiate from the point of impact in increasing particle size. The plastic layers usually hold the glass intact. When a second or third shot falls within the 6 inch diameter area of shattered glass, the bullets and shock waves do appreciably more damage to the window than was done by the first shot. Bulges on the inner surface formed of stretched plastic and fragmented glass are usually associated with the second and third shots. During the movement of plastic and glass as the bulges are formed, a shower of glass particles break loose from the outer surface of the bulged glass. The force with which the particles leave the glass varies on their nearness to the center of the shock wave and to the intensity of the shock wave as it passes through the glass. During the second and third shots the intensity through the weakened glass may be great enough to tear small discs of plastic and glass from the interior of the bulges.

An indicator placed 18 inches behind the bullet resisting glass is normally used to record the damage from flying glass particles. In the tests whose experimental data follows a 3/16 inch corrugated cardboard (200 lb. test) was used as the indicator material. Any penetra tion of the front cardboard surface in excess of one or two nicks one-eighth inch in length after three shots was considered sufficient penetration to fail the piece of glass being tested.

The objective of the present invention is twofold to produce economically a bullet resisting glass of minimum thickness which will stop or contain bullets spaced 4 inches apart in a triangular pattern in the approximate center of a 12 X 12 inch test sample of glass and at the same time pass the cardboard penetration test against flying glass particles when a cardboard indicator is mounted 18 inches behind the test sample. The test results are accumulated from firing done at the close range of feet or less. The ammunition used was rated as follows:

Bullet Muzzle Energy Muzzle Velocity Early testing was carried out using Remington 38 Super Automatic ammunition while later testing was carried out exclusively with Western Super X 38 Super Automatic ammunition. The latter ammunition is considered to consistently develop higher muzzle velocities. It is also considered that the latter ammunition is more destructive than the Remington ammunition. This consideration is based upon accumulated test data. 1

Samples were test fired while at room temperature of 70F., or after having been either frozen on one side for 3 hours at F. of after being heated in an oven at 120F. for three hours. Early in the testingit became evident that a structure passing the high temperature test 120F. for 3 hours) would pass the other two tests, also. Therefore, testing was carried out with test specimens which first had been heated in an ovenat 120F. for 3 hours.

Test data has indicated that the plastic bonding material, i.e., the 15 mil polyvinyl butyral used in the standard l 3/ 16 inch medium power bullet resisting glass, preferably should contain on the order of about 40 parts plasticizer in order to produce a bullet resisting glass capable of stopping or containing three Western Super X 38 caliber bullets. The standard 1 3/16 inch product laminated with polyvinyl butyral containing more than 40 parts plasticizer, forexample 43 parts 6 plasticizer, or 46 parts plasticizer, will not stop or contain three Western Super X 38 bullets. Usually the second or third bullet completely penetrated the specimen.

Our test effort concentrated on producing a medium power bullet resisting glass that would stop the three Western Super X 38 bullets while passing the spall penetration test. Variations in thicknesses of up to 1 9/16 inches were tested. Polyvinyl butyral with plasticizer contents of 31, 37.5, 40 and 43 parts were tested as well as the standard 46 parts plasticizer. As stated, polyvinyl butyral plastic bonding material with 40 parts or less plasticizer was required to stop the three Western Super X 38 bullets. However, standard 1 3/16 inch glass laminated with this plastic did not pass the spall penetration test at the elevated temperature.

Remarkably, however, it'was found that the incorporation of a void or air space between the inner face of the bullet resisting glass and the inclusion ofa fragment shield of laminated safety glass. or plastic was sufficient to stop the flying glass fragments and render the product safe.

A piece of standard 1 3/16 inch bullet. resisting glass was fabricated with a A; inch air space and a piece of lami-lami glass. The lami-lami glass was secured to the inner face of the bullet resisting glass with 3M foam tape having adhesive on both surfaces. After heating the glass to F. for 3 hours it was test fired with three Western Super X 38 bullets. It passed the penetration test even though the lami-lami shield was cracked by the bulges.

The same test was conducted using a /4 inch void between the bullet resisting glass and the transparent shield. In this case )4 inch foam tape was used to secure the lami-lami glass to the inner face of the bullet resisting glass. This fabrication also passed the spall penetration test after heating to 120F. for 3 hours. The laminated lami glass shield again was cracked by the bulges but remained intact.

Glass fragments which normally spall from the inner face of the bullet resisting glass are trapped in the air space. This may fill to a depth of 2 inches or more depending on the width of the air space. Physical contact is made between the bullet resisting glass and the laminated glass shield by the bulges following the second and third shots. It is believed that the shock wave after passing through the bullet resisting glass is absorbed by the air space. This is evident since the first shot into bullet resisting glass followed by a :6 inch air space does not crack the lami shield. The bulges which make contact with the lami shield do not have sufficient force to rupture the polyvinyl but'yral layer between the two pieces of lami glass.

Identical experiments were run using a piece of cellulose acetate butyrate plastic having a thickness of 0.060 inches in place of the laminated lami glass shield. The flexibility of the plastic sheet caused it to easily conform to the shape of the bulges in the bullet resisting glass.

Air spaces were later formed using V4. inch thick strips of wood to separate the fragment shield from the bullet resisting glass. The wood strips were used with equal facility. Since the bulges in the bullet resisting glass sometimes reached a height of three-fourths inches, an air space of seven-eighths inches was formed using wood spacers. This spacing is ideal if framing space is available.

plasticizer. The actual thickness of the piece after auto- EXPERI DATA claving is 1 3/32 inches. The aummunition used for the The following data is taken from a series of bullet retests was Western Super X 38 Automatic bullets.

Failed Zndand 3rd shots. 2 nicks inch laminated with 15 mil PVB containing 46 parts plasticizer. Thick- ,6 inch and V4 ness 1-9/16 inches inch plus needles heated at l 20F. for 3 hours. imbedded in cardboard.

FAILED TEST.

sisting tests. The standard make up of medium power 7 The immediately above test illustrates the effect of inbullet resisting glass consists of four sheets of )4; inch creasing thickness.

Failed 1st shot Heavy penetration of cardboard by Good 44.0 grams The immediately above test illustrates the effect of ad ditional pieces of inch glass.

glass and one sheet of /4; inch glass laminated with 15 mil polyvinyl butyral containing from 43 to 46 parts Type of No. of Weight of Sample Shots Spacing Fragments Penetration 4 pcs. V4 inch glass, 3 Good 35.7 grams Passed lst shot. 1 pc. 56 inch glass, Failed 2nd and 3rd 1 pc. micro glass laminshots cardated with 15 mil PVB board contained containing 40 parts 3 cuts A inch plasticizer. Thickness and several 1-5/32 inches heated at smaller nicksl20F. for 3 hours FAILED TEST.

5 pcs. inch glass, 3 Good 36.7 grams Passed lst shot. 1 pc. 54 inch glass lamin- 2nd and 3rd shots ated with 15 mil PVB were marginal containing 40 parts six nicks were plasticizer -Thickness found in card- 1-5/16 inches heated at board 56 inch [20F. for 3 hours long.

FAILED TEST.

Std. make up laminated 3 Good 6.10 grams All 3 shots with 15 mil PVB containpassed. lst did ing 46 parts plasticizer. not break cover A inch air space was shield. 2nd and formed by 3M tape around 3rd shots edges of glass. A fragment caused bulges shield of laminated lami which did break glass completed the make up. the cover glass. Overall thickness 1% inches Shield did not heated at 120F. for 3 hours rupture.

PASSED TEST.

Std. make up laminated 3 Good 5.51 grams All 3 shots with 15 mil PYB containpassed. 1st ing 46 parts plasticizer. did not break inch air space was cover glass.

provided by 3M foam tape. Laminated lami glass was used for fragmentation shield. Total thickness i 1% inches heated at 120F. for 3 hours.

2nd and 3rd shots caused bulges which did break cover glass. Penetration of cardboard by glass dust only. PASSED TEST.

-continued Type of No. of Weight of Sample Shots Spacing Fragments Penetration Std. make up laminated 3 Good 55.5 grams 1st and 2nd shots with mil PVB containing passed. 3rd 46 parts plasticizer. shot penetrated Mounted in frame with bullet resistinch air space formed by ing glass and /4 inch wood spacer and fragmentation fragmentation shield of shield. Several laminated lami glass. small nicks in Thickness of bullet resistcardboard ing glass 1-3/32 /4 inches FAILED TEST. air space 3/16 inches lami-lami glass heated at 120F. for 3 hours.

Std. make up laminated 3 Good None All 3 shots with 15 mil PVB containpassed. 2nd and ing 46 parts plasticizer. 3rd shots Test piece was mounted in caused heavy frame with V4 inch air bulges in glass. space formed by /4 inch inner face of wood spacer with .060 plastic was inch Uvex plastic as the abraded by fragmentation shield. fragments No Thickness 1-3/32 inches rupture occurred. V4 inch air space .060 inch PASSED TEST. Uvex heated at 120F. for 3 hours.

Std. Make up laminated 3 Good 11.00 grams No penetration with mil PVB containing 31 parts plasticizer Thickness 1-3/32 inches heated at 120F. for

3 hours.

Note: No fragment shield used with the immediately above test.

Std. make up laminated 3 Good with mil PVB containing 37.5 parts plasticizer. Thickness 1% inches. Heated at F.

for 3 hours.

11.8 grams Note: No fragment shield used with immediately above test.

Std. make up laminated 3 Good 31.2 grams with 15 mil PVB containing 46 parts plasticizer.

A '95 inch air space was formed using wood spacers with a laminated lami glass shield. Heated at 120F. for 3 hours.

Std. make up laminated 3 Good with 15 mil PVB containing 46 parts plasticizer.

Air space %inches with fragment shield of .060 inches Uvex" plastic.

20.0 grams .Thickness of glass 1-3/32 inches heated at 120F. for 3 hours.

Std. make up laminated 3 Good None with 25 mil PVB containing 37.5 parts plasticizer.

Glazed with 7| inch air space and .060 inch Uvex" fragment shield.

on 1st and 2nd shots. Several needles and fine fragments on 3rd shot. Marginal. FAILED TEST.

Passed 1st shot. 2nd shot marginal. 3rd shot failed. Several large particles embedded in cardboard.

FAILED TEST.

1st and 2nd shots passed. 3rd shot ventilated bullet resisting glass 7 and shield. Three small nicks in cardboard. PASSED TEST.

1st and 2nd shots passed.

3rd shot ventilated glass and forced one side of Uvex out of frame. No penetration of cardboard noted. PASSED TEST.

Bulges from 2nd and 3rd shots touched lami shield. The inside piece cracked on 3rd shot The outside piece did not break. All glass fragments were contained in the void.

PASSED TEST.

Bulges from 2nd and 3rd shots touched Uvex" shield. All glass fragments contained in void. PASSED TEST.

1 1 From the foregoing, it will be readily seen that a standard make up bullet resistance barrier with the further incorporation of an air barrier and a fragment shield will serve to provide an effective product which heretotion of any one of the barrier medium and bullet resisting glass from becoming airborne upon impact along y the path of movement of a projectile comprising a frame member, a lamination including a plurality of optical layers and interposed plastic material bonding layers, said plastic material bonding layers being significantly thinner in cross-section than any one of said optical layers and having an index of refraction substantially matching that of said optical layers, at least the optical layer furthermost from said impact point being of a thickness less than the thickness of the remaining optical layers of said lamination, a fragment shield'element, said lamination and element supported by said frame in parallel relation, and means for maintaining a space between said furthermost layer of said lamination and element.

2. The barrier of claim 1 wherein said barrier medium and bullet resisting glass are at least approxi mately 1 3/16 inches in thickness.

3. The barrier of claim 2 wherein said remaining optical layers each are one-fourth inch in thickness.

'4. The barrier of claim 2 wherein'said furthermost optical layer is one-eighth inch in thickness.

12 5. The barrier of claim 1 wherein each said plastic material bonding layer is of a thickness of from about l5 mils to about 30 mils.

6. The barrier of claim 5 wherein each said plastic material bonding layer is approximately 15 mils in thickness.

7. The barrier of claim 5 wherein each said plastic material bonding layer is formed of polyvinyl butyral having a plasticizer content of less than about 46 parts.

8. The barrier of claim 7 wherein said polyvinyl butyral has a plasticizer content of about 40 parts.

9. The barrier of claim 1 wherein each said optical layer is formed of glass.

10. The barrier of claim 1 wherein said furthermost optical layer is spaced from said element by a distance of at least one-eighth inch.

Ill. The barrier of claim 1 wherein said furthermost optical layer is spaced from said element by a distance of about at least seven-eighths inches.

12. The barrier of claim 1 wherein said element is a laminated body including at least two optical layers and interposed plastic bonding material layers, each of said interposed layers having a substantially matched index of refraction.

13. The barrier of claim 1 wherein said element is formed of cellulose acetate butyrate sheet having a thickness of about 0.060 inches.

14. The barrier of claim 11 wherein said element is formed by A inch tempered glass sheet.

15. The barrier of claim 11 wherein said element is formed by V4 inch float glass.

16. The barrier of claim 11 wherein said element is formed by A inch polished wire glass.

17. The barrier of claim 1 wherein said element is used with bullet resistant glass having a rating of at least medium power.

U NITED STATES "PA TE N 'I f AND. TRADEMARKOIFEI'CE CERTIFICATE, OF" CORRECTION- -PATENT NO. 3,917,391 DATED November 4, 1975 F are hereby corrected as shown below:'

INVENTOR( S) William C. Cooke f and A lber'c- H. Agate It 'is certifi ed that error appears in the above den tified pateni and that said Letters Patent Column 5, line 11, "varies-on their" shouldbe --varies depending 0;n"their-5." I

v Signed M A tres t:

UNITED STATES PATENT AND TRADEMARK OFFICE CERTIFICATE OF CORRECTION PATENT NO. 3,917,891

DATED November 4, 1975 |NVENTOR(S) William C. Cooke and Albert H. Agett It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:

Column 5, line 11, "varies on their" should be -varies depending on their.

Signed and Scaled this thirtieth D f March 1976 i [SEAL] Q Arrest:

ZZUTHV C. M A SON C. MARSHALL DANN mslmg Officer (ummissimwr ofPalenrs and Trademarks O DATED I are hereby corrected as shown below:

UNITED STATES "PATENT. AND TRADEMARK OFFICE CERTiFICATE OF- CORRECTION- 3,917,891 r 4 1 4 l November 4, 1975 r 4 INVENTOR(S) William C. Cqoke and Albert H. Agetfi PATENT NO.

If 'is certified that error appears in the above-identified patenf and tho? said Lotters Pafent -varies depending on their-" thr'rtieth [SEAL] s Dryers 1976 A nest:

RUTH C. MASON 

1. A BARRIER FOR USE AS A SHIELD TO PREVENT FRAGMENTATION OF ANY ONE OF THE BARRIER MEDIUM AND BULLET RESTING GLASS FROM BECOMING AIRBORNE UPON IMPACT ALONG THE PATH OF MOVEMENT OF A PROJECTILE COMPRISING A FRAME MEMBER, A LAMINATION INCLUDING A PLURALITY OF OPTICAL LAYERS AND INTERPOSED PLASTIC MATERIAL BONDING LAYERS, SAID PLASTIC MATERIAL BONDING LAYERS BEING SIGNIFICANTLY THINNER IN CROSS-SECTION THAN ANY ONE OF SAID OPTICAL LAYERS AND HAVING AN INDEX OF REFRACTION SUBSTANTIALLY MATCHING THAT OF SAID OPTICAL LAYERS, AT LEAST THE OPITCAL LAYER FUTHERMOST FROM SAID IMPACT POINT BEING OF A THICKNESS LESS THAN THE THICKNESS OF REMANING OPTICAL LAYERS OF SAID LAMINATION, A FRAGMENT SHIELD ELEMENT, SAID LAMINATION AND ELEMENT SUPPORTED BY SAID FRAME IN PARALLEL RELATION, AND MEANS FOR MAINTAININ A SPACE BETWEEN SAID FUTHERMOST LAYER OF SAID LAMINATION AND ELEMENT.
 2. The barrier of claim 1 wherein said barrier medium and bullet resisting glass are at least approximately 1 3/16 inches in thickness.
 3. The barrier of claim 2 wherein said remaining optical layers each are one-fourth inch in thickness.
 4. The barrier of claim 2 wherein said furthermost optical layer is one-eighth inch in thickness.
 5. The barrier of claim 1 wherein each said plastic material bonding layer is of a thickness of from about 15 mils to about 30 mils.
 6. The barrier of claim 5 Wherein each said plastic material bonding layer is approximately 15 mils in thickness.
 7. The barrier of claim 5 wherein each said plastic material bonding layer is formed of polyvinyl butyral having a plasticizer content of less than about 46 parts.
 8. The barrier of claim 7 wherein said polyvinyl butyral has a plasticizer content of about 40 parts.
 9. The barrier of claim 1 wherein each said optical layer is formed of glass.
 10. The barrier of claim 1 wherein said furthermost optical layer is spaced from said element by a distance of at least one-eighth inch.
 11. The barrier of claim 1 wherein said furthermost optical layer is spaced from said element by a distance of about at least seven-eighths inches.
 12. The barrier of claim 1 wherein said element is a laminated body including at least two optical layers and interposed plastic bonding material layers, each of said interposed layers having a substantially matched index of refraction.
 13. The barrier of claim 1 wherein said element is formed of cellulose acetate butyrate sheet having a thickness of about 0.060 inches.
 14. The barrier of claim 11 wherein said element is formed by 1/4 inch tempered glass sheet.
 15. The barrier of claim 11 wherein said element is formed by 1/4 inch float glass.
 16. The barrier of claim 11 wherein said element is formed by 1/4 inch polished wire glass.
 17. The barrier of claim 1 wherein said element is used with bullet resistant glass having a rating of at least medium power. 